Dispersion

The primary purpose of a diffraction grating is to disperse light spatially by wavelength. A beam of white light incident on a grating will be separated into its component wavelengths upon diffraction from the grating, with each wavelength diffracted along a different direction. Dispersion is a measure of the separation (either angular or spatial) between diffracted light of different wavelengths. Angular dispersion expresses the spectral range per unit angle, and linear resolution expresses the spectral range per unit length.

Angular Dispersion

The angular spread Δβ of a spectrum of order m between the wavelength λ and λ + Δλ can be obtained by differentiating the grating equation, assuming the incidence angle α to be constant. The change D in diffraction angle per unit wavelength is therefore

D = dβ/dλ = m / dcosβ = (m/d)secβ = Gm secβ   (2-13)

where β is given by Eq. (2-4). The quantity D is called the angular dispersion. As the groove frequency G = 1/d increases, the angular dispersion increases (meaning that the angular separation between wavelengths increases for a given order m).

In Eq. (2-13), it is important to realize that the quantity m/d is not a ratio which may be chosen independently of other parameters; substitution of the grating equation into Eq. (2-13) yields the following general equation for the angular dispersion:

D = dβ/dλ = (sinα + sinβ) / λcosβ   (2-14)

For a given wavelength, this shows that the angular dispersion may be considered to be solely a function of the angles of incidence and diffraction. This becomes even more clear when we consider the Littrow configuration (α = β), in which case Eq. (2-14) reduces to

D = dβ/dλ = (2/λ) tanβ, in Littrow.   (2-15)

When |β| increases from 10° to 63° in Littrow use, the angular dispersion can be seen from Eq. (2-15) to increase by a factor of ten, regardless of the spectral order or wavelength under consideration. Once the diffraction angle β has been determined, the choice must be made whether a finepitch grating (small d) should be used in a low diffraction order, or a coarse-pitch grating (large d) such as an echelle grating (see Section 12.5) should be used in a high order. [The fine-pitched grating, though, will provide a larger free spectral range; see Section 2.7 below.]

Linear dispersion

For a given diffracted wavelength λ in order m (which corresponds to an angle of diffraction β), the linear dispersion of a grating system is the product of the angular dispersion D and the effective focal length r'(β) of the system:

r'D = r'(dβ/dλ) = mr'/dcosβ = (mr'/d)secβ = Gmr'secβ (2-16)

The quantity r'Δβ = Δl is the change in position along the spectrum (a real distance, rather than a wavelength). We have written r'(β) for the focal length to show explicitly that it may depend on the diffraction angle β (which, in turn, depends on λ).

The reciprocal linear dispersion, formerly called the plate factor P, is more often considered; it is simply the reciprocal of r' D,

P = dcosβ / mr'   (2-17)

usually measured in nm/mm (where d is expressed in nm and r' is expressed in mm). The quantity P is a measure of the change in wavelength (in nm) corresponding to a change in location along the spectrum (in mm). [It should be noted that the terminology plate factor is used by some authors to represent the quantity 1/sinΦ, where Φ is the angle the spectrum makes with the line perpendicular to the diffracted rays (see Figure 2-6); in order to avoid confusion, we call the quantity 1/sinΦ the obliquity factor.] When the image plane for a particular wavelength is not perpendicular to the diffracted rays (i.e., when Φ ≠ 90°), P must be multiplied by the obliquity factor to obtain the correct reciprocal linear dispersion in the image plane.

Figure 2-6. The obliquity angle . The spectral image recorded need not lie in the plane perpendicular to the diffracted ray (i.e., Φ ≠ 90°).

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